硝酸铟
外观
硝酸铟 | |
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别名 | 硝酸铟(III) |
识别 | |
CAS号 | 13770-61-1(无水) ![]() 15650-88-1(三水) ![]() 264924-29-0(五水) ![]() |
性质 | |
化学式 | In(NO3)3 |
摩尔质量 | 300.839(无水) 354.887(三水) g·mol⁻¹ |
外观 | 无色固体(三水)[1] |
溶解性(水) | 易溶 |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
硝酸铟是一种无机化合物,化学式为In(NO3)3,存在无水物、一水物、三水物等。
制备
[编辑]硝酸铟的水合物可以通过铟和浓硝酸的反应制备。[2][3][4]
- In + 4 HNO3 → In(NO3)3 + NO + 2 H2O
无水硝酸铟通过氯化铟(III)和五氧化二氮反应得到。[5][3][6]
反应
[编辑]硝酸铟在硝酸根过量的环境下会形成[In(NO3)4]-离子。[2][3]
硝酸铟的水解会产生氢氧化铟。它也会和钨酸钠反应,视pH不同可得到In(OH)WO4、[In(OH)2]2WO4、NaInWO4、In2(WO4)3。[7][8]
参考资料
[编辑]- ^ 《化学化工物性数据手册》(无机卷). 刘光启等 主编. 化学工业出版社. P350. 表8.2.1 硝酸盐的物性总览.ISBN 7-5025-3591-8
- ^ 2.0 2.1 M. A. Malyarik; S. P. Petrosyants; A. B. Ilyukhin; Yu. A. Buslaev. Polyfunctionality of the nitrate group, coordination numbers of trivalent indium in nitrates complexes, and crystal structures of [In(NO3)(H2O)5](NO3)2 and HK6[In(NO3)4(H2O)2]3(NO3)4. Russian Journal of Inorganic Chemistry. 1993, 38 (12): 1849–1854. ISSN 0036-0236.
- ^ 3.0 3.1 3.2 D. G. Tuck; E. J. Woodhouse; P. Carty. Co-ordination compounds of indium. Part III. Indium(III) nitrate species. Journal of the Chemical Society A: Inorganic, Physical, Theoretical. 1966: 1077–1080. doi:10.1039/J19660001077 (英语).
- ^ Galina V. Kozhevnikova; Gábor Keresztury. The state of indium ions in nitrate solutions: A Raman spectroscopic study. Inorganica Chimica Acta. 1985, 98 (1): 59–65. doi:10.1016/S0020-1693(00)90751-5 (英语).
- ^ 《无机化学丛书》.第二卷 铍 碱土金属 硼 铝 镓分族. P613. 3.17.3 第VA族含氧酸盐. (1)硝酸盐
- ^ B. O. Field; C. J. Hardy. Volatile and anhydrous nitrato-complexes of metals: preparation by the use of dinitrogen pentroxide, and measurement of infrared spectra. Journal of the Chemical Society. 1964: 4428–4434. doi:10.1039/JR9640004428 (英语).
- ^ Keita Yura; Karl C. Fredrikson; Egon Matijević. Preparation and properties of uniform colloidal indium compounds of different morphologies. Colloids and Surfaces. 1990, 50: 281–293. doi:10.1016/0166-6622(90)80270-E (英语).
- ^ Shcherbina, K. G.; Mokhosoev, M. V.; Gruba, A. I. Reaction of aluminum and indium nitrates with sodium tungstate in hot solutions [in Russian]. Zhurnal Neorganicheskoi Khimii, 1974. 19 (2): 396-399. ISSN 0044-457X.
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