1-溴-1-甲基环己烷
外观
1-溴-1-甲基环己烷 | |
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识别 | |
CAS号 | 931-77-1 ![]() |
PubChem | 12502129 |
SMILES |
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性质 | |
化学式 | C7H13Br |
摩尔质量 | 177.08 g·mol−1 |
沸点 | 42 °C(15 mmHg) 79 °C(38 mmHg)[1] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
1-溴-1-甲基环己烷是一种有机化合物,化学式为C7H13Br,它是溴甲基环己烷的同分异构体之一。
合成
[编辑]1-溴-1-甲基环己烷可由1-甲基环己烯和氢溴酸反应得到,吸附剂使用硅胶。[2]它也可由甲基环己烷和溴在紫外线照射下反应得到。[3]
参考文献
[编辑]- ^ G. F. Dvorko, I. V. Koshchii, E. A. Ponomareva. Kinetics and mechanism of unimolecular heterolysis of cage-like compounds: XIX. Effect of the nucleofuge nature on the activation parameters of heterolysis of 1-halo-1-methylcyclohexanes in cyclohexane. Heterolysis rate ratio in aprotic and protic solvents. Russian Journal of Organic Chemistry. 2007-01, 43 (1): 50–55 [2023-02-17]. ISSN 1070-4280. doi:10.1134/S1070428007010046 (英语).
- ^ Kiyoshi Tanemura. Silica gel-mediated hydrohalogenation of unactivated alkenes using hydrohalogenic acids under organic solvent-free conditions. Tetrahedron Letters. 2018-12, 59 (49): 4293–4298 [2023-02-17]. doi:10.1016/j.tetlet.2018.10.043. (原始内容存档于2022-10-23) (英语).
- ^ Manabe, Yoshiyuki; Kitawaki, Yuriko; Nagasaki, Masahiro; Fukase, Koichi; Matsubara, Hiroshi; Hino, Yoshiko; Fukuyama, Takahide; Ryu, Ilhyong. Revisiting the Bromination of C-H Bonds with Molecular Bromine by Using a Photo-Microflow System. Chemistry - A European Journal (Wiley). 2014-08-29, 20 (40): 12750–12753. ISSN 0947-6539. doi:10.1002/chem.201402303.