乙醯丙酮釤是一種配位化合物,化學式為Sm(C5H7O2)3,或簡寫為Sm(acac)3。它可以和N-溴代丁二醯亞胺在三氯甲烷中反應,得到淺黃色的Sm(Br-acac)3(其中Br-acac為3-溴代-2,4-戊二酮配體)。[1]它的水合物在DMSO中重結晶,可以得到Sm(acac)3·2DMSO·H2O。[2]
它和八羰基二鈷反應,可以用於製備SmCo5。[3]
- ^ Gopalan Shankar, Suthamalli K. Ramalingam. Phenylisocyanation and bromination studies on lanthanide ?-diketonates. Transition Metal Chemistry. 1984, 9 (12): 449–453 [2021-09-20]. ISSN 0340-4285. doi:10.1007/BF00620675 (英語).
- ^ Dzyubenko, N. G.; Kalenichenko, Yu. V.; Martynenko, L. I. Rare earth tris(acetylacetonate) adducts with DMSO(俄文). Zhurnal Neorganicheskoi Khimii, 1988. 33 (1): 52-58.
- ^ Hongwei Gu, Bing Xu, Jiancun Rao, R. K. Zheng, X. X. Zhang, K. K. Fung, Catherine Y. C. Wong. Chemical synthesis of narrowly dispersed SmCo5 nanoparticles. Journal of Applied Physics. 2003-05-15, 93 (10): 7589–7591 [2021-09-20]. ISSN 0021-8979. doi:10.1063/1.1537697. (原始內容存檔於2021-09-17) (英語).