乙酸銩
外觀
乙酸銩 | |
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英文名 | Thulium(III) acetate |
別名 | 醋酸銩 |
識別 | |
CAS號 | 39156-80-4 ![]() |
性質 | |
化學式 | Tm(CH3COO)3 |
外觀 | 晶體 |
溶解性(水) | 可溶 |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
乙酸銩是銩的乙酸鹽,化學式為Tm(CH3COO)3,它以無水物和四水合物[1]的形式存在。
性質
[編輯]乙酸銩和乙醯丙酮鐵在丁二醇中於300 °C反應,可以得到六方晶系的TmFeO3。[2]
- Tm(CH3COO)3 + 3 CF3COOH → Tm(CF3COO)3 + 3 CH3COOH
參考文獻
[編輯]- ^ K. I. Petrov, M. G. Zaitseva, L. M. Sukova. Spectroscopic study of thulium acetate tetrahydrate single crystals. Journal of Applied Spectroscopy. 1971-08-01, 15 (2): 1058–1060 [2019-02-01]. ISSN 1573-8647. doi:10.1007/BF00607309 (英語).
- ^ Masashi Inoue, Toshihiro Nishikawa, Tomohiro Nakamura, Tomoyuki Inui. Glycothermal Reaction of Rare-Earth Acetate and Iron Acetylacetonate: Formation of Hexagonal ReFeO3. Journal of the American Ceramic Society. 1997, 80 (8): 2157–2160 [2019-02-01]. ISSN 1551-2916. doi:10.1111/j.1151-2916.1997.tb03103.x (英語).
- ^ S. I. Gutnikov, E. V. Karpova, M. A. Zakharov, A. I. Boltalin. Thulium(III) trifluoroacetates Tm(CF3COO)3 · 3H2O and Tm2(CF3COO)6 · 2CF3COOH · 3H2O: Synthesis and crystal structure. Russian Journal of Inorganic Chemistry. 2006-04-01, 51 (4): 541–548 [2019-02-01]. ISSN 1531-8613. doi:10.1134/S0036023606040061 (英語).
拓展閱讀
[編輯]
- Mondry, A., & Bukietyńska, K. (2003). The power and limits of the Judd—Ofelt theory: a case of Pr3+ and Tm3+ acetates and dipicolinates. Molecular Physics, 101(7), 923-934.
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