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2,5-雙脫氧-SZ-685C

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2,5-雙脫氧-SZ-685C
IUPAC名
(3S)-1,3,8-Trihydroxy-6-methoxy-3-methyl-2,4-dihydro-1H-anthracene-9,10-dione
識別
CAS號 97400-70-9  checkY
PubChem 5459129
ChemSpider 9510649
SMILES
 
  • C[C@]1(CC(C2=C(C1)C(=O)C3=CC(=CC(=C3C2=O)O)OC)O)O
InChI
 
  • 1/C16H16O6/c1-16(21)5-9-13(11(18)6-16)15(20)12-8(14(9)19)3-7(22-2)4-10(12)17/h3-4,11,17-18,21H,5-6H2,1-2H3/t11-,16-/m0/s1
InChIKey LRHFZXBVDMVFCW-ZBEGNZNMBC
性質
化學式 C16H16O6
摩爾質量 304.29 g·mol−1
外觀 橙黃色針狀晶體[1]
熔點 162-164 °C(1S,3R
183-185 °C(1S,3S[1]
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

2,5-雙脫氧-SZ-685C(英語:Austrocortilutein)(1,2,3,4-四氫-1,3,8-三羥基-6-甲氧基-3-甲基-9,10-蒽醌)是一種有機化合物,化學式為C16H16O6,其英文名「austrocortirubin」源自於澳大利亞的絲膜菌屬(Cortinarius)的毒蕈。[2]它可以用於製備3-脫氧交替酚A。[3]

參考文獻

[編輯]
  1. ^ 1.0 1.1 Melvyn Gill, Albin F. Smrdel, Richard J. Strauch and Michael J. Begley. Pigments of fungi. Part 12. Structure and absolute stereochemistry of antibiotic tetrahydroanthraquinones from the fungus Dermocybe splendida Horak. X-Ray structure determination of austrocortirubin phenylboronate and austrocortilutein acetonide. J. Chem. Soc., Perkin Trans. 1, 1990, 1583-1592. doi:10.1039/P19900001583.
  2. ^ Melvyn Gill; Richard J. Strauch (1985). New tetrahydroanthraquinones from the genus Cortinarius. Tetrahedron Letters, 26 (21), 2593–2596. doi:10.1016/s0040-4039(00)98845-2.
  3. ^ Burns, CJ; Gill, M; Gimenez, A (1991). Pigments of Fungi. XXIV. New Trihydroxylated Tetrahydroanthraquinones From an Australian Fungus Belonging to the Genus Dermocybe. Australian Journal of Chemistry, 44 (12), 1729–1736. doi:10.1071/ch9911729.