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二氯二溴甲烷

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二氯二溴甲烷
别名 二溴二氯甲烷
二氯二溴化碳
NSC 6198
识别
CAS号 594-18-3  checkY
性质
化学式 CBr2Cl2
摩尔质量 242.72 g·mol−1
熔点 38 °C(311 K)[1]
沸点 150.2 °C(423.3 K)[1]
135 °C(408 K)[2]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

二氯二溴甲烷是一种有机化合物,化学式为CBr2Cl2。它可由四氯化碳三溴化铝的反应制得。[3]它与烯烃以溴和二氯溴甲基发生加成反应。[4][5]

参考文献

[编辑]
  1. ^ 1.0 1.1 "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2021-11-02].
  2. ^ Lecomte, Jean; Volkringer, Henri; Tchakirian, Arakel. Infrared and Raman spectra of chlorobromomethanes. Compt. rend., 1937. 204: 1927-1929.
  3. ^ Tanaka, Ryuichi; Zheng, Shi Qin; Kawaguchi, Kenji; Tanaka, Takehide. Nucleophilic attack on halo(phenyl)​acetylenes by halide ions. Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1980. 11: 1714-1720.
  4. ^ Bo Chen, Cheng Fang, Peng Liu, Joseph M. Ready. Rhodium-Catalyzed Enantioselective Radical Addition of CX 4 Reagents to Olefins. Angewandte Chemie International Edition. 2017-07-17, 56 (30): 8780–8784 [2021-11-02]. PMC 5672916可免费查阅. PMID 28544237. doi:10.1002/anie.201704074. (原始内容存档于2021-11-05) (英语). 页面存档备份,存于互联网档案馆
  5. ^ British Library. Lending Division; Chemical Society (Great Britain). Russian Chemical Reviews. British Library Lending Division. 1994 [2021-11-02]. (原始内容存档于2021-11-05).  |issue=被忽略 (帮助)页面存档备份,存于互联网档案馆