溴碘甲烷
外观
溴碘甲烷 | |
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IUPAC名 Bromoiodomethane | |
识别 | |
CAS号 | 557-68-6 ![]() |
PubChem | 68407 |
ChemSpider | 61690 |
SMILES |
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InChI |
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性质 | |
化学式 | CH2BrI |
摩尔质量 | 220.84 g/mol g·mol⁻¹ |
外观 | 液体 |
密度 | 2.926 g/cm3(17 °C) |
熔点 | 1 °C |
沸点 | 139.5 °C |
危险性 | |
警示术语 | R:R37/38 R41 |
安全术语 | S:S26 S36/39 |
欧盟分类 | 刺激性 (Xi) |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
它的临界点为367.85 °C和6.3 MPa,折射率为1.6382 (20 °C, D)。
参考文献
[编辑]- Tarnovsky A. N., Wall M., Gustafsson M., Lascoux N., Sundström V., Åkesson E. Ultrafast Study of the Photodissociation of Bromoiodomethane in Acetonitrile upon 266 nm Excitation. J. Phys. Chem. A. March 2002, 106 (25): 5999–6005(7) [2007-06-29]. doi:10.1021/jp014306j. (原始内容存档于2007-09-29).
- Liu Y.-J., Ajitha D., Krogh J. W., Tarnovsky A. N., Lindh R. Spin-Orbit Ab Initio Investigation of the Photolysis of Bromoiodomethane. ChemPhysChem. December 2005, 7 (4): 955–963(9) [2007-06-29]. PMID 16596616. doi:10.1002/cphc.200500654. (原始内容存档于2011-08-13).
- Zheng, X.; Phillips, D. L. Photoisomerization reaction of CH2BrI following A-band and B-band photoexcitation in the solution phase: Transient resonance Raman observation of the iso-CH2I-Br photoproduct. J. Chem. Phys. August 2000, 113 (8): 3194–3203(10). Bibcode:2000JChPh.113.3194Z. doi:10.1063/1.1286920.
- Liu K., Zhao H., Wang C., Zhang A., Ma S., Li Z. A theoretical study of bond selective photochemistry in CH2BrI. J. Chem. Phys. January 2005, 122 (4): 044310 [2007-06-29]. PMID 15740251. doi:10.1063/1.1835955.
外部链接
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